Superconducting Fluctuation Corrections to the Thermal Current in Granular Metals

The first-order superconducting fluctuation corrections to the thermal conductivity of a granular metal are calculated. A suppression of thermal conductivity proportional to $T_c/(T-T_c)$ is observed in a region not too close to the critical temperature $T_c$. As $T\simeq T_c$, a saturation of the correction is found, and its sign depends on the ratio between the barrier transparency and the critical temperature. In both regimes, the Wiedemann-Franz law is violated.Comment: 9 pages, 7 figures. Replaced with published version. Important change

Local risk-minimization under the benchmark approach

© 2014, Springer-Verlag Berlin Heidelberg. We study the pricing and hedging of derivatives in incomplete financial markets by considering the local risk-minimization method in the context of the benchmark approach, which will be called benchmarked local risk-minimization. We show that the proposed benchmarked local risk-minimization allows to handle under extremely weak assumptions a much richer modeling world than the classical methodology

CHALLENGES AND OPPORTUNITIES FOR THE IMPLEMENTATION OF H-BIM WITH REGARDS TO HISTORICAL INFRASTRUCTURES: A CASE STUDY OF THE PONTE GIORGINI IN CASTIGLIONE DELLA PESCAIA (GROSSETO – ITALY)

Historical Building Information Modeling (H-BIM) has been widely documented in literature and is becoming more popular with government bodies, who are increasingly choosing to make its use mandatory in public procurements and contracts. Although the system seems to be one of the best approaches for managing data and driving the decision-making process, several difficulties arise due to the amount of effort required in the initial phases, when the data derived from a geometrical survey must be converted into parametric elements. Moreover, users must decide on a “level of geometrical simplification” a long time in advance, and this inevitably leads to a loss of geometrical data. From this perspective, our research describes a procedure to optimize the workflow of information for existing artefacts, in order to achieve a “lean” H-BIM. In this article, we will analyse two aspects: the first relates to the level of accuracy in a digital model created from the two different point clouds achieved from laser scanner and form images, while the second concerns the conversion of this information into parametric elements (Building Object Models- BOMs) that need to have specific characteristics. The case study we are presenting is the “Ponte Giorgini” (“Giorgini Bridge”) in Castiglione della Pescaia (Grosseto – Italy)

Halo-complexes of Titanium(III): the Thermochromic Behaviour of [NBu4][TiCl4(thf)2]

TiCl3(thf)3 reacts with ACl (A = NBu4, PPN; PPN = Ph3PNPPh3) in dichloromethane solution, affording the compounds A[TiCl4(thf)2] (A = NBu4, 1; A = PPN, 2). Compound 1, dissolved in CH2Cl2, exhibits thermochromic behaviour which has been the subject of variable-temperature UV–Vis investigations

The Irish Revolution, 1916-23

This is the author accepted manuscript. The final version is available from Oxford University Press via http://dx.doi.org/10.1093/ehr/cew05

Nucleation of superconducting pairing states at mesoscopic scales at zero temperature

We find the spin polarized disordered Fermi liquids are unstable to the nucleation of superconducting pairing states at mesoscopic scales even when magnetic fields which polarize the spins are substantially higher than the critical one. We study the probability of finding superconducting pairing states at mesoscopic scales in this limit. We find that the distribution function depends only on the film conductance. The typical length scale at which pairing takes place is universal, and decreases when the magnetic field is increased. The number density of these states determines the strength of the random exchange interactions between mesoscopic pairing states.Comment: 11 pages, no figure

Individualised headband simulation test for predicting outcome after percutaneous bone conductive implantation.

Trans-cutaneous bone conduction (BC) stimulators, when coupled to the HB (BC-HB), are generally used to predict the results that could be achieved after bone conductive implant (BCI) surgery, and their performance is generally considered inferior to that provided by the definitive percutaneous system. The aim of the present study was to compare the performances between BC-HB and BCI of the same typology, when the former's sound processor is fitted in accordance to the individual auditory situation. Twenty-two patients selected for surgical application of a BCI were evaluated and the same audiological protocol was used to select the candidate and assess the final outcome. The BC-HB was properly fitted based on individual hearing loss and personal auditory targets, and tested as primary step of the protocol to obtain the most reliable predictive value. The BAHA Divino and BP100 sound processors were applied in 12 patients with conductive/mixed hearing loss (CMHL) and in 10 subjects with single sided deafness (SSD). Audiometric evaluation included the pure tone average (PTA3) threshold between 250-1000 Hz; the PTA thresholds at 2000 and 4000 Hz; intelligibility scores as percentage of word recognition (WRS) in quiet and in noise; and subjective evaluation of perceived sound quality by a visual analogue scale (VAS). Statistical evaluation with a student's t test was used for assessment of efficacy of BC-HB and BCI compared with the unaided condition. Spearman's Rho coefficient was used to confirm the reliability of the BC-HB simulation test as a predictor of definitive outcome. The results showed that the mean PTA difference between BCI and BC-HB ranged from 2.54 to 8.27 decibels in the CMHL group and from 1.27 to 3.9 decibels in the SSD group. Compared with the BC-HB, BCI showed a better WRS both in CMHL (16% in quiet and 12% in noise) and in SSD (5% in quiet and a 1% in noise) groups. Spearman's Rho coefficient, calculated for PTA, WRS in quiet and in noise and VAS in the two aided conditions, showed a significant correlation between BC-HB and BCI, between PTA and VAS and between WRS in quiet and VAS. It is possible to conclude that the headband test, when the sound processor of the selected bone conductive implant is fitted and personalised for individual hearing loss and auditory targets of the candidate, may provide highly predictive data of the definitive outcome after BCI implant surgery

Photovoltaic characterization of di-branched organic sensitizers for DSSCs.

In this work, the data on the effect of peripheral functionalization of a series of triphenylamine based di-branched dyes used as sensitizers in dye-sensitized solar cells are presented. The effect of different alkyl functionalities on the donor moiety upon the optical and photovoltaics parameters have been investigated in dye-sensitized solar cells (DSSCs) using a 10-μm TiO2 active layer. The absorption spectra, output efficiency, and incident photon to conversion efficiency of the DSSCs have been collected. The data can be exploited for properly designing efficient, stable, and industrially viable dyes for third generation solar devices

Selective changes in inhibition as determinants for limited hyperexcitability in the insular cortex of epileptic rats

The insular cortex (IC) is involved in the generalization of epileptic discharges in temporal lobe epilepsy (TLE), while seizures originating in IC can mimic the epileptic phenotype seen in some TLE patients. Few studies have however addressed the changes occurring in the IC in TLE animal models. Here, we analyzed the immunohistochemical and electrophysiological properties of IC networks in non-epileptic control and pilocarpine-treated epileptic rats. Neurons identified with a neuron-specific nuclear protein antibody showed similar counts in the two types of tissue but parvalbumin- and neuropeptide Y-positive interneurons were significantly decreased (parvalbumin, approx. -35%; neuropeptide Y, approx. -38%; P<0.01) in the epileptic IC. Non-adapting neurons were more frequently seen in the epileptic IC during intracellular injection of depolarizing current pulses. In addition, single-shock electrical stimuli elicited network-driven epileptiform responses in 87% of epileptic and in 22% of non-epileptic control neurons (P<0.01) but spontaneous postsynaptic potentials had similar amplitude, duration and intervals of occurrence in the two groups. Finally, pharmacologically isolated, GABAA receptor-mediated inhibitory postsynaptic potentials had more negative reversal potential (P<0.01) and higher peak conductance (P<0.05) in epileptic tissue. These data reveal moderate increased network excitability in the IC of pilocarpine-treated epileptic rats. We propose that such limited degree of hyperexcitability originates from loss of parvalbumin- and neuropeptide Y-positive interneurons that is compensated by an increased drive for GABAA receptor-mediated inhibition